Application Exercise 4: Global Climate Change

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1. Understanding Earth’s energy balance is essential to understanding the issue of global warming. For example, the solar energy striking Earth’s surface averages 168 watts per square meter (W/m²), but the energy leaving Earth’s surface averages 390 W/m². Why isn’t Earth cooling rapidly?

Even though the amount of energy emitted is more than double the amount received, Earth does not cool rapidly because the atmosphere retains much of the emitted energy.

2. Describe & explain where the stamen is correct or incorrect. Explain. 

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When temperature measurements are extrapolated into the future, predictions made by Arrhenius of a 5–6 °C rise in the average temperature of the planet’s surface may need to be revised. Current estimates from the United Nations predict that average temperatures will increase somewhere between 1.4 °C and 5.8 °C (2.5 °F and 10.4 °F) by the year 2100. Other scientists, looking at a possible doubling of CO 2 emissions in the future, estimate a temperature increase between 1.0 °C and 3.5 °C (1.8 °F and 6.3 °F). Future temperature changes can be influenced, at least to a considerable extent, by the human beings who inhabit this planet. We are a long way from the out-of-control hothouse of Venus, but we face difficult decisions. These decisions will be better informed with an understanding of the mechanism by which greenhouse gasses interact with radiation to create the greenhouse effect. For that, we must again take a submicroscopic view of matter. 

3. One of the first radar devices developed during World War II used microwave radiation of a specific wave range that triggers the rotation of water molecules. Why was the design not successful?

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One of the first radar devices developed during World War II used microwave radiation of a wavelength that triggers the rotation of water molecules. This was unfortunate because:

i. it heated up the air around the machine.

ii. it caused diseases in the operators of the radar.

iii. absorption of microwave radiation by water in the atmosphere interferes with the detection of intended objects.

4. Now that you have studied air quality (Unit 1), stratospheric ozone depletion (Unit 2), and global warming (Unit 3), which do you believe poses the most serious problem for you in the short run (pick one and explain)? In the long run (pick one and explain why)?

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Answers will likely depend a little on geography. Air quality will likely be the most serious short term concerns of my group, especially with the speed industrial is growing. Take a look at quality of air from Beijing, polluted by the factories or the cost saving method that result in haze and deforestation in Indonesia. The ozone hole is probably too far removed for students like us to have felt the impact directly. Depending on the perceptions of seriousness of climate change, ozone layer depletion will likely be the most serious long term concern we have.

 

Application Exercise 3: Energy from Combustion

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  1. From personal experience, state whether these processes are endothermic or exothermic. Give a reason for each.

a. A charcoal briquette burns

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Exothermic. A charcoal briquette releases heat as it burns.

b. Water evaporates from your skin

Endothermic. Water absorbs the heat necessary for evaporation from your skin, and your skin feels cooler.

c. Ice melts

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Endothermic. Ice absorbs the necessary heat to melt from the environment.

  1. Chemical explosions are very exothermic reactions. Describe the relative bond strengths in the reactants and products that would make a good explosion.

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The bond energies involved are: C–H single bonds, 416 kJ/mole; O=O double bonds, 498 kJ/mole; H–O single bonds, 467 kJ/mole; C=O double bonds, 803 kJ/mole. The bond energies of the products are larger than those of the reactants. This will lead to a large negative net energy change indicating an exothermic reaction.

  1. How might you explain the difference between temperature and heat to a friend? Use some practical, everyday examples?

Wouldn’t you rather spill a drop of hot coffee on you than the whole cupful at the same temperature? Although the drop and the cup full of coffee may initially have the same temperature, you will receive a bigger burn from the bigger volume of coffee because it has the higher heat content. Heat is a form of energy. In contrast, temperature is a measurement that indicates the direction heat will flow. Heat always flows from an object at high temperature to an object at lower temperature. This means that if hot coffee is added to cold coffee, heat will flow from the hot liquid to the cold liquid, and the final temperature of the mixture will be between the original temperatures of the two individual solutions. Heat depends on the temperature and on how much material is present.

  1. A premium gasoline available at the most stations gas an octane rating of 98. What does that tell you about:

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a. The knocking characteristics of this gasoline

Gasoline with an octane rating of 98 has the same knocking characteristics as a mixture composed of 98% isooctane and 2% n-heptane. As a “premium gasoline,” it has a higher octane rating than other blends sold at gasoline stations and hence is more resistant to knocking than these blends.

b. Whether the fuel contains oxygenates

The octane rating provides no information about whether or not the fuel contains oxygenates. Other labels around the pump should reveal this information.