Monthly Archives: February 2017

Week 7 – Unit 5: Water We Drink Q&A

Q1) How can you purify your water when you are hiking? Name two or three possibilities. Compare these methods in terms of cost and effectiveness. Are they any of these methods similar to those used to purify municipal water supplies? Explain.

Method Cost Effectiveness
Sedimentation No cost Straightforward method however it may take a longer time for particles and dirt to settle
Boiling water Need for source of heat/fire  Easy to obtain pure, potable water (with bacteria removed etc)
Water purification droplets or tablets Can be costly Straightforward and kill bacteria and viruses quickly
Evaporation trap Materials needed are not very costly  Time consuming and require a lot of effort to construct the evaporation trapsolar-still-diagrams

Municipal water purification methods include fluoridation, chlorination, coagulation, sedimentation and filtration to name a few. When hiking, the several methods available for us to obtain pure water follow the same approach as the municipal purification method.

For example, using sedimentation to obtain purified water is similar to the setting process in the municipal purification process. After sedimentation, filtration is required as well in order to separate the water from impurities.

municipal-water

 


Q2) Explain why desalination techniques, despite proven technological effectiveness, are not used more widely to produce potable drinking water.

Desalination involves removes ions from seawater, namely NaCl. NaCl is an ionic compound that consist of both Na+ and Cl ions. When dissolved in water, the ions will form ion dipole attractions with the water molecules as shown below.

picture1

These attractions are very strong and would require high amounts of energy to overcome. Energy consumption for the desalination process would hence be high making the process very costly in addition to the high cost of the technology used. Furthermore, the brine residue results in environmental concerns when being disposed.


Q3) Water quality in a chemical engineering building on campus was continuously monitored because testing indicated water from drinking fountains in the building had dissolved lead levels above those established by NEA.

a. What is the likely major source of the lead in the drinking water?

Major source of the lead is likely to come from corroded lead and iron pipes that distributes water to those drinking fountains. Due to the corrosion, lead seeps into the moving water and thus resulting in higher levels of dissolve lead in them.

b. Do the research activities carried out in this chemistry building account for the elevated lead levels found in the drinking water? Explain.

No, the research activities carried out in the chemical building may have nothing to do with the elevated lead levels found in the drinking water. There are several factors that may cause corrosion in the lead and iron pipelines, such as pH of the water, the amount of oxygen in the water, temperature of the water and the velocity of the water.


Q4) Some vitamins are water-soluble, whereas others are fat-soluble. Would you expect either or both to be polar compounds? Explain.

Both the water soluble and fat soluble vitamins would be polar compounds. The reason why water soluble vitamins are polar is because it has many polar parts such as -OH and C=O-O as seen in Figure 1, in which there are lone pairs in the O. Hence these areas are very electronegative, which results in the net dipole moment of the water soluble vitamins to be more negative than fat soluble vitamins. As such,more inter molecular hydrogen bonds can be formed between the hydrogen from one of the –OH with the lone pair from the oxygen from the another polar part such as –OH and C=O-O.

picture12

Figure. 1

picture1

Figure. 2

Fat soluble vitamins are also polar,just that it is less polar than water soluble vitamins.

As seen in Figure 2,the fat soluble vitamins usually have a long chain of carbon and hydrogen bonds,which is non polar.Hence the only polar areas in fat soluble vitamins would be those with –OH. Hence,the overall dipole moment of fat soluble vitamins are less negative as compared water soluble  vitamins. Therefore, it is not very soluble in water since it does not form much inter molecular hydrogen bonds in water.

Week 6 – Unit 3: The Chemistry of Global Climate Change Q&A

picture1

Q1) Understanding Earth’s energy balance is essential to understanding the issue of global warming. For example, the solar energy striking Earth’s surface averages 168 watts per square meter (W/m2), but energy leaving Earth’s surface averages 390 W/m2. Why isn’t Earth cooling rapidly?

Even though the energy leaving Earth’s surface is more than twice that of the solar energy striking the Earth’s surface, Earth isn’t cooling rapidly because of Earth maintain her energy balance.

The emitted energy does not go directly out into space, but instead it is reabsorbed by clouds and gases in the atmosphere. Majority of the energy are reabsorbed by greenhouse gases such as methane, nitrous oxides, carbon dioxide etc. These greenhouse gases will constantly emit energy back into the atmosphere and keep the Earth a habitable temperature.

Ultimately, most of the energy will make its way out back into space and those that doesn’t are the ones responsible for the phenomenon known as global warming.


Q2) Decide and explain whether the statement is correct or incorrect. Explain.

The statement is incorrect. The winter mentioned in the cartoon is not due to the effect of higher average temperature caused by global warming but as a result of the effect of extreme weather and climate changes caused by global warming. Therefore, the issue of global warming is still more present than ever and we should not rest on our laurels.


Q3) One of the first radar devices developed during World War II used microwave radiation of a specific wave range that triggers the rotation of water molecules. Why was the design not successful?

Water molecules will absorb the the microwave radiation and hence it the water molecules will rotate.However,this design is not successful during the WWII as the water molecules will interfere with the intended content that the radar device is suppose to detect.


Q4) Now that you have studied air quality (Unit 1), stratospheric ozone depletion (Unit 2), and global warming  (Unit 3), which do you believe poses the most serious problem for you in the short run (pick one and explain)? In the long run (pick one and explain why)?

In the short run, air quality poses the most serious problem. Its effects can be seen in days. Even now, industrialised countries with many factories like China are already facing air pollution issues, with air quality reaching hazardous levels. People are already facing health problems and premature deaths due to air pollution. In Singapore, when mass burning of forests occur in Indonesia every year, air quality in Indonesia & neighbouring countries can reach dangerous levels and people fall ill as a result. Air pollution’s adverse effects on people’s health and productivity can be seen even now.

In the long run, I think that global warming poses the most serious problem. An increase in global temperatures can disrupt ecosystems. Rising sea levels also have the potential to lead to entire countries and islands becoming submerged under the sea. Extreme weather conditions can also pose threats to safety across the world. The agricultural sector may be the most affected because it is the most reliant on external weather conditions, which will lead to even more food source problems across the world on top of affecting the livelihood of many families depending on agriculture for a living.

 

Week 5 – Unit 4: Energy from Combustion Q&A

Qn 1) From personal experience, state whether these processes are endothermic or exothermic. Give a reason for each.

  1. A charcoal briquette burns.
    Exothermic. As a charcoal briquette burns, it releases heat.
  2. Water evaporates from your skin.
    Endothermic. Water absorbs the heat necessary for evaporation from your skin, and your skin feels cooler.
  3. Ice melts.
    Endothermic. Ice absorbs the necessary heat from the environment to melt.

Qn 2) Chemical explosions are very exothermic reactions. Describe the relative bond strengths in the reactants and products that would make for a good explosion.

A good explosion is defined as one that produces  a lot of energy. Explosions are exothermic reactions as they generate energy. For exothermic reactions, the amount of energy released from forming bonds is more than the energy absorbed from breaking the bonds. The relative bond strength is directly proportional to the bond energy. Therefore, the magnitude of the bond strength for the products must be larger than that of the reactants, to lead to an enthalpy change that is as negative as possible which would then lead to a good exothermic reaction and hence a good explosion.

1

Qn 3) How might you explain the difference between temperature and heat to a friend? Use some practical, everyday examples?

Temperature is a measure of the average kinetic energy of the particles in an object, it determines how ‘hot’ or ‘cold’ something is. On the other hand, heat is energy that flows from a hotter to a colder region.

Example: There are two cups of water one at 25°C while the other is at 70°C. The one at 70°C would have a higher temperature due to the average kinetic energy in the water being higher than that of the one at 25°C. When you mix both liquids together, heat will be transferred from the water at 70°C to the water at 25°C due to the temperature difference.

2-jpg

Qn 4) A premium gasoline available at most stations has an octane rating of 98. What does that tell you about:

  1. the knocking characteristics of this gasoline?
    A premium gasoline with an octane rating of 98 means that it has a knocking characteristics of 98% isooctane and 2% heptane.

  2. whether the fuel contains oxygenates?
    If the fuel contain oxygenates, it should give an octane rating of >100, since the oxygenates such as ethanol and MTBE (methyl tertiary-butyl ether) will raise the octane rating to make it better than the “standard”, which is isooctane with an octane rating of 100.

Ozone

We learned about the difference between using the terminologies “ozone layer” and “ozone screen”. Also, we discussed why it is improbable to create ozone and transport it to the stratosphere.

Firstly, the expression “ozone layer” creates the image of the ozone as a form of protection whereas “ozone screen” gives off the idea that it is very thin and UV rays can easily penetrate.

As aerosols rapidly break down the ozone layer (since CFCs are the catalysts for the breakdown), the rate at which the ozone is depleting is too rapid and quick that sending ozone to the stratosphere will not be enough. Also, large amount of energy is needed to transport ozone hence it is not feasible.

 

index-39

Thinning of Ozone Layer

Our ozone layer is thinning because of the excessive use of aerosol products, such as CFCs, which releases a large amount of chlorine atoms into the atmosphere. The chlorine atoms acts as catalysts for the decomposition of ozone, thus resulting in the thinning of ozone layer. This is detrimental for us as the thinning of ozone layer would mean that more UV rays will penetrate and will damage our genetic materials (DNA).